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In recent studies we have investigated the water retention behavior of hydroxyethyl cellulose (HEC) and carboxymethyl hydroxyethyl cellulose (CMHEC) in oil well cement, respectively. We found that the working mechanism of HEC relies on a dual effect, namely its enormous intramolecular water sorption (binding) capacity and a concentration dependent formation of hydrocolloidal associated polymer networks [23]. Contrary to this, the working mechanism of CMHEC changes with dosage. At low dosages (up to ~ 0.3% by weight of cement), adsorption presents the predominant mode of action, whereas above a certain threshold concentration (the “overlapping” concentration), formation of associated polymer networks is responsible for its effectiveness [24].
Cellulose ether plays an important role in mortar in three aspects: first, it has excellent water retention capacity, second, it has an impact on mortar consistency and thixotropy, and third, it interacts with cement.